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Isothermal (vapor + liquid) equilibria and excess enthalpy data of {1-hexene + methyl butyl ether (MBE)} and {1-hexene + methyl tert-butyl ether (MTBE)} binary systems at several temperatures

Identifieur interne : 000945 ( Main/Exploration ); précédent : 000944; suivant : 000946

Isothermal (vapor + liquid) equilibria and excess enthalpy data of {1-hexene + methyl butyl ether (MBE)} and {1-hexene + methyl tert-butyl ether (MTBE)} binary systems at several temperatures

Auteurs : Rachida Hani [Algérie] ; Roland Solimando [France] ; Latifa Negadi [Algérie] ; Jacques Jose [France] ; Ahmed Ait Kaci [Algérie]

Source :

Journal of chemical thermodynamics [ 0021-9614 ] ; 2012.

RBID : Pascal:12-0405914

Abstract

The vapor pressures of {1-hexene+ methyl butyl ether (MBE)} and {1-hexene + methyl tert-butyl ether (MTBE)) binary mixtures and of the three pure components were measured by means of a static device at temperatures between (263 and 333) K. The data were correlated with the Antoine equation. From these data, excess Gibbs functions were calculated for several constant temperatures and fitted to a third-order Redlich-Kister equation using the Barker's method. Additionally, molar excess enthalpies, H^E, for the two binary systems have been measured at 303.15 K using an isothermal flow calorimeter.

Affiliations:

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<front><div type="abstract" xml:lang="en">The vapor pressures of {1-hexene+ methyl butyl ether (MBE)} and {1-hexene + methyl tert-butyl ether (MTBE)) binary mixtures and of the three pure components were measured by means of a static device at temperatures between (263 and 333) K. The data were correlated with the Antoine equation. From these data, excess Gibbs functions were calculated for several constant temperatures and fitted to a third-order Redlich-Kister equation using the Barker's method. Additionally, molar excess enthalpies, H<sup>E</sup>
, for the two binary systems have been measured at 303.15 K using an isothermal flow calorimeter.</div>
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Isothermal (vapor + liquid) equilibria and excess enthalpy data of {1-hexene + methyl butyl ether (MBE)} and {1-hexene + methyl tert-butyl ether (MTBE)} binary systems at several temperatures

Isothermal (vapor + liquid) equilibria and excess enthalpy data of {1-hexene + methyl butyl ether (MBE)} and {1-hexene + methyl tert-butyl ether (MTBE)} binary systems at several temperatures

Source :

Abstract

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